Chopped (9 p.m., Food) -- Season 40 starts with firefighters cooking to prove that they are cool under pressure.
MLB All-Star Game (8 p.m., Fox) -- Nationals Park in Washington, D.C., hosts the 89th All-Star baseball game.
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No Passport Required (9 p.m., PBS / UNC-TV) -- Chef Marcus Samuelsson explores the influence of Vietnamese culture on New Orleans, from pho to banh mi.
The Last Defense (10 p.m., ABC) -- The prosecution’s star witness testifies he was with Oklahoma college student Julius Jones he pulled the trigger, but a critical piece of evidence is never seen by the jury.